First, download and install theWearOSapp from the App Store on your iPhone.
Launch the app and tap on the arrow button to pair your Watch with the iPhone.
Now, swipe left on your watch andchoose the language.

Now, iPhone will prompt you the grant the permissions.
Once done, you will see the Watch code.
Tap the watch code for the selected watch you wish to connect to the iPhone unit.

The Android Wear app on the iPhone would then take a stab at pair with your iPhone.
This could take some time, so be patient at that time and let the process complete.
Once the syncing is completed, your watch will be connected to the iPhone gadget.

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